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New Hg (II) Complex: As a Novel, Green and Efficient Reusable Catalyst for Synthesis of Polyhydroquinolines via Hantzsch Condensation

1, 2,4, 3,5, 2,4, 3,5

  1. 1PhD student of chemistry, Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, IRAN.
  2. 2Assistant Professor, Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, IRAN.
  3. 3Associate Professor, Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, IRAN.
  4. 4Assistant Professor, Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, IRAN.
  5. 5Associate Professor, Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, IRAN.

CORRESPONDENCE

Sadegh Allameh

Assistant Professor, Department of Chemistry, Mashhad Branch, Islamic Azad University, Mashhad, IRAN.

sadgeh_allameh@yahoo.com

Received: 10-02-2018; Accepted: 24-04-2018.

Volume 7, Issue 1 · pp. 17-20 · 2018 · DOI:

ABSTRACT

A novel Hg (II) complex based on 5-nitro-N1-((pyridin-2-yl) methylene) benzene-1,2-diamine (HgL2) has been studied for catalytic performance in the synthesis of polyhydroquinoline derivatives. This efficient and eco-friendly catalyst has been utilized in a one-pot four-component Hantzsch condensation of dimedone, aromatic aldehydes, ethyl acetoacetate and ammonium acetate under solvent and free-solvent conditions. Mild reaction conditions, simple work-up procedure, being environmentally friendly and high product yields are advantageous feature of this method

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    Ghasemi, H. D., Allameh, S., Beyramabadi, S. A., Behmadi, H., & Morsali, A. M. (2018). New Hg (II) Complex: As a Novel, Green and Efficient Reusable Catalyst for Synthesis of Polyhydroquinolines via Hantzsch Condensation. Asian Journal of Biological and Life Sciences, 7(1), 17-20.

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    © 2018 Author(s)

    This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 International License, which permits unrestricted use, distribution and reproduction in any medium, provided the original author and source are credited. CC BY 4.0